21. “Isotopic Probing of Molecular Oxygen Activation at Copper(I) Sites.” M.P. Lanci, V.V. Smirnov, C.J. Cramer, E.V. Gauchenova, J. Sündermeyer J.P. Roth* J. Am. Chem. Soc. 2007, ASAP 10/26/07.
20.
“The First Crystal Structure of a Monomeric Phenoxyl Radical: 2,4,6-Tri-tert-butylphenoxyl Radical” V.W. Manner, T.F. Markle, J. H. Freudenthal, J. P. Roth, J. M. Mayer* Chem. Comm. 2007, in press.
19. "Molecular
Oxygen Dependent Steps in Fatty Acid Oxidation by Cyclooxygenase-1
(COX-1)" A. Mukherjee, D. W. Brinkley, K-M. Chang, J. P. Roth* Biochemistry, 2007, 46, 3975-3989.
18. "Advances in Studying Bioinorganic
Reaction Mechanisms: Isotopic Probes of Activated Oxygen Intermediates
in Metalloenzymes." J. P. Roth* Curr. Opin. Chem.
Biol., 2007, 11, 142-150.
17. “Mechanisms
of Electron Transfer in Catalysis by Copper Zinc Superoxide
Dismutase.” V. V. Smirnov and J. P. Roth* J. Am. Chem. Soc.2006,
128, 16424-5.
16. “Oxygen
Isotope effects upon Reversible O2-Binding Reactions:
Characterizing Mononuclear Superoxide and Peroxide Structures.”
M. P. Lanci, J. P. Roth*J. Am. Chem. Soc. 2006, 128, 16006-7.
15. “Probing
Metal-Mediated O2 Activation in Chemical and Biological
Systems.” V. V. Smirnov, D. W. Brinkley, M. P. Lanci,
K. D. Karlin, J. P. Roth* J. Molec. Catal. A 2006, 251,
100-107.
14. “Stoichiometric
Oxidations of Sigma-Bonds: radical and Possible Non-Radical
Pathways.” J. M. Mayer*, E. A. Mader, J. P. Roth, J.
M. Bryant, T. Matsuo, A. Dehestani, B. C. Bales, E. J. Watson,
T. Osaka, K. Valliant-Saunders, W. H. Lam, D. A. Hrovat, W.
T. Borden, E. J. Davidson J. Molec. Catal. A 2006, 251,
24-33.
13. “Evidence
for Cu-O2 Intermediates in Superoxide Oxidations
by Biomimetic Copper(II) Complexes.” V. V. Smirnov, J. P. Roth* J. Am. Chem. Soc. 2006, 128,
3683-3695.
12. “Oxygen Kinetic Isotope
effects as Probes of Enzymatic Activation of Molecular Oxygen.” J.
P. Roth*, J. P. Klinman* Isotope Effects in Chemistry
and Biology, Kohen, A. and Limbach, H.-H. Eds. CRC Press:
Boca raton, FL, 2006, 645-669.
11. “Determination
of a Large Reorganization Energy Barrier for Hydride Abstraction
by Glucose Oxidase.” D. W. Brinkley, J.P. Roth*J. Am. Chem. Soc. 2005
127,15720-15721.
10. “Structures
of Transition States in Metal-Mediated O2 Activation
Reactions.” M. P. Lanci, D. W. Brinkley, K. L. Stone,
V. V. Smirnov, J.P. Roth* Angew. Chem. Int.
Ed. 2005, 44, 7273-7276.
9. “Bifunctional
Lewis Acid-Nucleophile-Based Asymmetric Catalysis: Mechanistic
Evidence for Imine Activation Working in Tandem with Chiral
Enolate Formation in the Synthesis of beta-Lactams.”
S. France, M.H. Shah, A. Weatherwax, H. Wack, J.P. Roth, T. Lectka* J. Am. Chem. Soc.,
2005, 127, 1206-1215
8. “Kinetic
Isotope Effects.” J. P. Roth and J. P. Klinman*
Encycl. Biol. Chem., Lennarz, W.J.;
Lane, M. D. Eds., Elselvier, San Diego, 2004,
2, 522-527.
7. “Oxygen
Isotope Effects on Electron Transfer to O2 Probed
Using Chemically Modified Flavins Bound to Glucose Oxidase.”
J. P. Roth,* R. Wincek, G. Nodet, D. E. Edmondson, W. S. McIntire, J. P. Klinman* J. Am. Chem. Soc. 2004, 126, 15120-15131.
6. “Electron
and Hydrogen Atom Self-Exchange Reactions of Iron and Cobalt
Coordination Complexes.” J.
C. Yoder, J. P. Roth,* E. M. Gussenhoven, A. Larsen, J.
M. Mayer*J. Am. Chem. Soc.2003, 125, 2629-2640.
5. “Catalysis
of Electron Transfer during O2 Activation by the
Flavoprotein Glucose Oxidase.” J. P. Roth,
J. P. Klinman* Proc. Nat. Acad.
Sci., USA 2003, 100, 62-67.
4. “Application
of the Marcus Cross Relation to Hydrogen Atom Transfer Reactions
of Transition Metal Complexes.”
J. P. Roth, J. C. Yoder, T.-J. Wan, J. M. Mayer* Science
2001, 294, 2524-2526.
3. “Intrinsic
Barriers for Electron and Hydrogen Atom Transfer Reactions
of Biomimetic Iron Complexes.” J. P. Roth, S. Lovell
, J. M. Mayer*J. Am. Chem. Soc.
2000, 122, 5486-5498.
2. “Hydrogen
Atom Abstraction by Transition Metal Complexes.” J.
M. Mayer, J. P. Roth, K. Wang Preprints of Symposia
- ACS, Div. Fuel Chem. 1999,
44, 434-436.
1. “Hydrogen
Transfer Reactivity of a Ferric Bi-imidazoline Complex That
Models the Activity of Lipoxygenase Enzymes.” J.
P. Roth, J. M. Mayer* Inorg. Chem. 1999,
38, 2760-2761.
|
| 21. 2nd International Interdisciplinary Conference on Vitamins, Coenzymes and Biofactors Athens, GA (10/08)
20. Pennsylvania State University (03/07)
19. Protein
Derived Cofactors, Radicals, and Quinones Gordon Research
Conference; Ventura, CA (01/08)
18. Stable Isotope
Tools for Assessment of Chemical and Microbial Transformation
Reactions in Complex Natural and Contaminated Environments
Mt. Verita, Switzerland (11/07)
17. Strategies in Enzymatic Oxidation Catalysis 234th National American Chemical Society Meeting, Boston, MA (08/07).
16. Enzymes,
Co-enzymes and Metabolic Pathways Gordon Research Conference;
Biddeford, ME (07/07).
15. Fifth Internation Congress on Isotopes
2007 Castellón, Spain (05/07)
14. Montana State
University (05/04/07).
13. University of
Wisconsin, Madison (05/02/07).
12. Georgetown University
(03/07)
11. Inorganic
Reaction Mechanisms Gordon Research Conference; Ventura,
CA (02/07)
10. Georgia State
University (10/27/06)
9. ACS Southwest
Regional Meeting Houston, TX "Living at the Interface:
Challenges in Interdisciplinary Research" (10/21/06).
8. Metals
in Biology Gordon Research Conference; Ventura, CA (01/06).
7. ADHOC-2005
(Activation of Dioxygen and Homogeneous Catalytic
Oxidation, 9th International Symposium) University
of Cologne, Cologne, Germany (07/05).
6. University
of Delaware (04/05).
5. University
of North Carolina, Chapel Hill (03/05).
4. Randolph-Macon
College (11/04).
3. Isotopes
in Chemical and Biological Sciences Gordon Research Conference;
Ventura, CA (02/04).
2. Photosynthesis
Gordon Research Conference; Bristol, RI (06/03).
1. Symposium for Hydrogen
Bonding in Inorganic Chemistry 216th National American
Chemical Society Meeting, Boston, MA (08/98). |